This ACP Special Issue seeks to report research advancements in the understanding of mercury sources, distribution pathways, levels, physicochemical characterization, measurement traceability, impacts on global ecosystems, and policy-relevant information presented at the ICMGP 2019 and being developed under the MercOx (Metrology of oxidized mercury) project and two ERA-PLANET initiatives – Integrative and Comprehensive Understanding on Polar Environments (iCURE) and Integrated Global Observing Systems for Persistent Pollutants (iGOSP). The Special Issue is open to all publications related to the scope of the Special Issue.

This special issue includes papers based on recent field campaigns, including US Department of Energy Aerosol and Cloud Experiments in Eastern North Atlantic (ACE-ENA), NASA North Atlantic Aerosols and Marine Ecosystems Study (NAAMES), and the North Atlantic Climate System Integrated Study (ACSIS), and long-term measurements from observatories (e.g., the Atmospheric Radiation Measurement Eastern North Atlantic site on Graciosa Island in the Azores). Presently the responses of marine low-cloud systems to changes in atmospheric greenhouse gases and aerosols are major sources of uncertainty that limit our ability to predict future climate. Major contributions to this uncertainty derive from poor understanding of the cloud responses to aerosol changes and the natural aerosol state that is being perturbed by anthropogenic emissions. One overarching scientific objective of these recent field campaigns is to understand key processes that drive the properties and interactions of aerosol and clouds under representative meteorological and cloud conditions. Another important focus is to validate and improve ground-based retrieval algorithms using comprehensive in situ aircraft measurements. This will lead to high-quality, long-term datasets from the routine ground-based remote sensing, which allow greater statistical reliability in the observed properties and relationships among aerosols, clouds, and precipitation than is possible with the aircraft measurements alone.

The project Effect of Megacities on the Transport and Transformation of Pollutants on the Regional and Global Scales, EMeRGe, was created to experimentally investigate the transport and transformation of air plumes coming from major population centres, MPCs. It comprises a set of unique airborne measurement campaigns carried out in two parts of the world having MPCs of very different characteristics and emissions. The two measurement campaigns using the HALO research aircraft (www.halo-spp.de) were conducted in Europe in summer 2017 and in East Asia during the intermonsoon period in March-April 2018. The initial scientific team of EMeRGe, comprising scientists from four German universities and four research centres in 2016 (www.iup.uni-bremen.de/emerge/), was extended within the EMeRGe international membership, incorporating more than 50 research partners from 16 different countries. The combined and synergetic set of information obtained from airborne and ground-based data, satellite products, and their comparison with models enables the patterns of atmospheric composition and meteorological parameters observed during the campaigns to be constrained and thereby our understanding of the emissions, their transport, and physico-chemical transformation of the outflow from MPC emissions to be tested and assessed. The EMeRGe special issue aims to publish the scientific results achieved by the project EMeRGe. This comprises contributions of the partners of the national and international EMeRGe scientific community. It solicits all relevant submissions addressing the EMeRGe science objectives.

The Wave-driven ISentropic Exchange (WISE) mission is a collaborative research project to investigate transport and mixing processes in the upper troposphere and the lower stratosphere (UTLS) over the Atlantic. Headed by Forschungszentrum Jülich GmbH and the Johannes Gutenberg University of Mainz, 14 measurement flights were conducted with the high-altitude research aircraft HALO in September and October 2017 from Shannon, Ireland. Further partners providing instrumentation were the Karlsruhe Institute for Technology (KIT), the German Aerospace Center (DLR), the universities of Heidelberg, Frankfurt am Main, and Wuppertal, and the German National Metrology Institute. The scientific flights were supported by a team of about 90 persons.

The main objective of this project is to study the relation between chemical composition and the dynamical structure of the UTLS with a focus on the following topics: (i) interrelation of the tropopause inversion layer (TIL) and trace gas distribution, (ii) role of planetary wave breaking for water vapor transport into the extratropical lower stratosphere, (iii) role of halogenated substances for ozone and radiative forcing in the UTLS region, and (iv) occurrence and effects of sub-visual cirrus (SVC) in the lowermost stratosphere.

The special issue mainly includes papers from the airborne measurement campaign itself but is also open to other studies close to the topic. This includes both advanced scientific analyses of observational and measured data during the campaign as well as related climatological studies, but also manuscripts based on instrumental developments.

The Aerosol Chemistry Model Intercomparison Project (AerChemMIP) is endorsed by the Coupled-Model Intercomparison Project 6 (CMIP6) and is designed to quantify the climate and air-quality impacts of aerosols and chemically reactive gases. Specifically, the aim of AerChemMIP is to answer four scientific questions. 1. How have anthropogenic emissions contributed to global radiative forcing and affected regional climate over the historical period? 2. How might future policies (on climate, air quality, and land use) affect the abundances of NTCFs and their climate impacts? 3. How do uncertainties in historical NTCF emissions affect radiative forcing estimates? 4. How important are climate feedbacks to natural NTCF emissions, atmospheric composition, and radiative effects? This special issue is to be devoted to papers that analyse targeted simulations with CMIP6 climate models to address these questions as well as papers that evaluate these models against observations. It also includes papers from other CMIP6-related activities (e.g. RFMIP, DAMIP), containing contributions to the understanding of climate forcing and feedbacks involving aerosols, reactive gases, and associated biogeochemical cycles.